| 02.06.2012 | La Paz | Hernando Siles | 34 389 |
| Bolivia | 0:2 (0:1) | Chile |
| [12] Daniel Vaca, [2] Luis Mendez, [3] Luis Gutierrez, [4] Cristian Vargas, [5] Ronald Rivero, [6] Walter Flores, [7] Juan Carlos Arce, [10] Jhasmani Campos, [13] Alejandro Chumacero, [18] Ricardo Pedriel, [20] Pablo Escobar | [1] Claudio Bravo, [5] Pablo Contreras, [6] Osvaldo Gonzalez, [7] Alexis Sanchez, [8] Arturo Vidal, [9] Humberto Suazo, [13] Jose Rojas, [14] Matias Fernandez, [15] Eugenio Mena, [20] Charles Aranguiz, [21] Marcelo Diaz |
| Coach:Gustavo Quinteros | Claudio Borghi (ARG) |
| Scorers: | 45'+2 Charles Aranguiz, 83' Arturo Vidal |
| Substitutions:56' in [22] Rudy Cardozo out Jhasmani Campos, 70' in [21] Augusto Andaveris out Ricardo Pedriel, 73' in [11] Alcides Pena out Pablo Escobar |
73' in [17] Luis Figueroa out Matias Fernandez, 78' in [11] Eduardo Vargas out Humberto Suazo, 87' in [2] Braulio Leal out Charles Aranguiz |
| Cautions:13' Jhasmani Campos, 53' Luis Mendez, 57' Ronald Rivero, 67' Walter Flores, 72' Augusto Andaveris | 61' Eugenio Mena |
| Expulsions:53' Luis Gutierrez |   |
| Referee:Alfredo Intriago (ECU) Fourth Official:Omar Ponce (ECU) |
Assistant referee:Juan Cedeno (ECU), Christian Lescano (ECU) |